Nernst's heat theorem.

-
According to Nernst, “ The heat capacities of all solids tend to zero as the absolute zero of temperature is approached and that the internal energies and entropies of all substances become equal there, approaching their common value asymptotically tending to zero ”. 
Usually it is called as third law of thermodynamics.

Comments

Post a Comment

Popular posts from this blog

What is Freundlich adsorption isotherm ?

-
Image
Explanation:- The variation in the amount of gas adsorbed by the adsorbent with pressure at constant temperature can be expressed by means of a curve termed as adsorption isotherm. According to freundlich isotherm,     The extent of adsorption of a gas per unit mass of adsorbent depends upon the pressure of that gas. I.e Look at the Graph,(x/m) vs (p) Equation (1) is the general form of freundlich adsorption isotherm. Case-1( at low pressure) If  x/m =kp¹ That implies 1/n=1 I.e  n=1 So at low pressure freundlich adsorption isotherm holds good because initially their is more adsorption occur. Case-2 (at high pressure) If x/m=constant  i.e1/n=0 That implies n=infinity So at high pressure x/m independent on pressure because after saturation pressure their is no adsorption occur due to no space on adsorbent. At saturation pressure Amount of gas adsorbed=amount of gas desorbed. Look at the logarithm graph of equation (1) This is all about freundlich adsor
Read more

Difference between molecularity & order of reaction

-
Answer:-                                      order of Molecularity                                reaction       Common points:- • It's value does not         •Its value also  exceed three.                      does not exceed                                              three. • Depends upon the          •It also depends  Condition of a react           upon the conidti ion.                                       on of a reaction.  Difference points:- • It is always a whole         • It may be posit number,non-zero,non-      ive or negative in negative.                              teger, zero, frac-                                                tion. • It can be obtained            • It can obtai- from a simple balanced       ned only         chemical reaction.                 experimental-                                                  y.                                                   
Read more