Second order phase transitions.

-
Second order phase transitions can be defined as the phenomenon that takes place with no change in entropy & volume at constant temperature & pressure.
e.g
 ★ Transition of a ferromagnetic material to a paramagnetic material at the curie point.
★ Order-disorder transitions in chemical compounds & alloys.

Comments

Post a Comment

Popular posts from this blog

What is Freundlich adsorption isotherm ?

-
Image
Explanation:- The variation in the amount of gas adsorbed by the adsorbent with pressure at constant temperature can be expressed by means of a curve termed as adsorption isotherm. According to freundlich isotherm,     The extent of adsorption of a gas per unit mass of adsorbent depends upon the pressure of that gas. I.e Look at the Graph,(x/m) vs (p) Equation (1) is the general form of freundlich adsorption isotherm. Case-1( at low pressure) If  x/m =kp¹ That implies 1/n=1 I.e  n=1 So at low pressure freundlich adsorption isotherm holds good because initially their is more adsorption occur. Case-2 (at high pressure) If x/m=constant  i.e1/n=0 That implies n=infinity So at high pressure x/m independent on pressure because after saturation pressure their is no adsorption occur due to no space on adsorbent. At saturation pressure Amount of gas adsorbed=amount of gas desorbed. Look at the logarithm graph of equation (1) This is al...
Read more

Difference between molecularity & order of reaction

-
Answer:-                                      order of Molecularity                                reaction       Common points:- • It's value does not         •Its value also  exceed three.                      does not exceed                                              three. • Depends upon the          •It also depends  Condition of a react           upon the conidti ion.                                       on of a reaction.  Dif...
Read more